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钠离子电池研究进展
引用本文:叶飞鹏,王莉,连芳,何向明,田光宇,欧阳明高.钠离子电池研究进展[J].化工进展,2013,32(8):1789-1795.
作者姓名:叶飞鹏  王莉  连芳  何向明  田光宇  欧阳明高
作者单位:1.北京科技大学材料科学与工程学院,北京100083;2清华大学核能与新能源技术研究院,北京100084; 3清华大学汽车安全与节能国家重点实验室,北京100084
基金项目:国家自然科学基金,国家973计划,科技部国际合作,清华大学自主科研计划,汽车安全与节能国家重点实验室重点基金(ZZ2012-011)项目。
摘    要:钠离子电池具有比能量高、安全性能好、价格低廉等优点,在储能领域有望成为锂离子电池的替代品。本文阐述了钠离子电池的研究现状,对钠离子电池研究的正负极材料、电解质的制备以及其电化学性能作了概述性讨论。正极材料有氧化物型、聚阴离子型;负极材料有碳基材料、钛基材料和合金负极材料等;电解液有有机溶剂电解液和凝胶聚合物电解液,并分别阐明了各种材料的优势和局限性。最后指出了这类高效钠二次电池体系有可能逐渐替代锂离子电池,并指明了现阶段发展钠离子的主要问题是不同体系材料的相互匹配。

关 键 词:钠离子电池  正极  负极  电解质  

Advance in Na-ion batteries
YE Feipeng , WANG Li , LIAN Fang , HE Xiangming , TIAN Guangyu , OUYANG Minggao.Advance in Na-ion batteries[J].Chemical Industry and Engineering Progress,2013,32(8):1789-1795.
Authors:YE Feipeng  WANG Li  LIAN Fang  HE Xiangming  TIAN Guangyu  OUYANG Minggao
Affiliation:1School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083,China;2Institute of Nuclear & New Energy Technology,Tsinghua University,Beijing 100084,China;3State Key Laboratory of Automotive Safety and Energy,Tsinghua University,Beijing 100084,China
Abstract:Na-ion battery is one of the possible replacements for Li-ion battery for energy storage,due to its high energy density,high safety,and low cost. In this paper,research progress of Na-ion batteries is reviewed,including preparation and electrochemical performance of positive electrodes,negative electrodes and electrolytes. Positive electrodes include oxides,phosphates. Negative electrodes include carbon based-anodes,titanium based-anodes and alloy anodes. Electrolytes include organic electrolytes and gel polymer electrolytes. The advantages and limitations of materials are presented. Na-ion secondary battery could gradually replace Li-ion battery,and the present main problem is matching of different system materials.
Keywords:Na-ion battery  positive electrode  negative electrode  electrolyte
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