Sensory characterization and identification of odorous constituents in acrylic adhesives |
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| Affiliation: | 1. Friedrich-Alexander-Universität Erlangen-Nürnberg, Emil Fisher Center, Department of Chemistry and Pharmacy, Henkestraße 9, 91054 Erlangen, Germany;2. Department Sensory Analytics, Fraunhofer Institute for Process Engineering and Packaging IVV, Giggenhauser Straße 35, 85354 Freising, Germany;1. Laboratório de Análises de Resíduos de Pesticidas (LARP), Departamento de Química, Universidade Federal de Santa Maria, 97105-900 Santa Maria-RS, Brazil;2. Escola de Química e Alimentos, Universidade Federal do Rio Grande (FURG), 95500-000, Santo Antônio da Patrulha-RS, Brazil;1. College of Materials Science and Art Design, Inner Mongolia Agricultural University, Hohhot, China;2. Inner Mongolia Key Laboratory of Sandy Shrubs Fibrosis and Energy Development and Utilization, Hohhot 010000, China;1. Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, 33 Fucheng Road, Beijing 100048, PR China;2. Beijing Higher Institution Engineering Research Center of Food Additives and Ingredients, Beijing Technology and Business University, 33 Fucheng Road, Beijing 100048, PR China;3. Department of Food, Nutrition and Packaging Sciences, Clemson University, Clemson, SC 29634, USA;1. Research School of Chemistry, Australian National University, Canberra, ACT, Australia;2. School of Chemistry and Molecular Biosciences, University of Queensland, Brisbane, Qld, 4072, Australia |
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| Abstract: | Most products in our surroundings contain adhesives, including acrylic adhesives which are used in many industry sectors. Some of these adhesives contain solvents that produce strong odors, but even adhesives which are produced without solvents can emit intensive or pungent odors. In the latter case, the odor may arise from monomers in the adhesive product, from manufacturing by-products or from degradation products. Here we analyzed several acrylic, methacrylic and benzyl acrylic adhesives to identify representative odorous contaminants. The volatile fraction of the products was extracted and isolated by solvent-assisted flavor evaporation (SAFE), then analyzed via high-resolution gas chromatography olfactometry (HRGC-O), HRGC-mass spectrometry (HRGC-MS/O) and two-dimensional HRGC-MS/O. Aroma extract dilution analysis was carried out to determine the most prominent odorants. Using this targeted odorant-analytical approach, we identified 27 odorous substances representing diverse classes of molecules, including phenols with leather-like, horse stable-like or medicinal odors, acrylates eliciting glue-like, moldy and fruity impressions, and different esters with honey-like or effervescent tablet-like smells. These results show that the odor of acrylic adhesives results from a mixture of different odorants that cannot generally be traced back to the main constituents of the product but are rather likely to stem from impurities and trace side products and other contaminants. |
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| Keywords: | Gas chromatography olfactometry (GC-O) Mass spectrometry (MS) D: health and safety environmental issues |
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