TOMAC为载体的大块液膜法处理含镍废水 |
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引用本文: | 李海红,;朱恩云,;宗刚,;仝攀瑞.TOMAC为载体的大块液膜法处理含镍废水[J].西北纺织工学院学报,2008(6):729-732. |
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作者姓名: | 李海红 ;朱恩云 ;宗刚 ;仝攀瑞 |
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作者单位: | [1]西安工程大学环境与化学工程学院,陕西西安710048 |
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基金项目: | 基金项目:陕西省教育厅专项科研计划项目(06JK294) |
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摘 要: | 研究了三辛基甲基氯化铵(TOMAC)为载体的大块液膜体系处理含镍(Ⅱ)废水.应用正交实验考察了料液相中金属离子浓度、载体浓度、反萃剂浓度、料液相pH对镍(Ⅱ)迁移的影响.结果表明,镍(Ⅱ)迁移的最优方案为料液相中金属离子浓度为0.03mol/L,载体浓度为6%,反萃剂浓度为0.05mol/L,料液相pH为10.在最优条件下,迁移时间180min,迁移率可达53.92%.因素的影响主次为镍(Ⅱ)浓度〉料液相pH〉载体浓度〉反萃剂浓度.
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关 键 词: | 大块液膜 三辛基甲基氯化铵 含镍废水 液膜分离 |
Treatment of Nickel wastewater with bulk liquid membrane using TOMAC as carrier |
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Affiliation: | LI Hai-hong , ZHU En-yun, ZONG Gang, TONG Pan-rui (School of Environmental & Chemical Eng. , Xitan Polytechnic University, Xi'an 710048, China) |
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Abstract: | The treatment of Nickel wastewater with bulk liquid membrane using TOMAC as carrier was studied. The effects of the concentration of Ni( Ⅱ ) in feed phase, the concentration of carrier in membrane phase, the concentration of HCl in strip phase and pH value in feed phase on the transport of Ni ( Ⅱ ) were researched through orthogonal design. The results show that the transport rate of Ni( Ⅱ ) can reach 53.92% under the optimal conditions of the concentration of Ni( Ⅱ ) in feed phase, the concentration of carrier in membrane phase, the concentration of HCl in strip phase and pH value in feed phase were 0.03mol/L, 6M, 0.05mol/L and 10, respectively, when the transport time was 180 min. In addition, the order of the effects on the transport rate of Ni( Ⅱ ) is the concentration of Ni( Ⅱ ) 〉 pH value in feed phase〉 carrier concentration 〉 the concentration of stripping agent. |
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Keywords: | bulk liquid membrane tri-n-octylmethylammonium chloride(TOMAC) Nickel wastewater liquid membrane separation |
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