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Lightweight concretes of activated metakaolin-fly ash binders,with blast furnace slag aggregates
Affiliation:1. Department of the Built Environment, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands;2. Van Gansewinkel Minerals, Flight Forum 240, 5600 CE Eindhoven, The Netherlands;1. Department of Materials and Ceramic Engineering, CICECO — Aveiro Institute of Materials, University of Aveiro, Campus Universitário de Santiago, 3810-193 Aveiro, Portugal;2. Mobility Engineering Center, Federal University of Santa Catarina (UFSC), 89218-000 Joinville, SC, Brazil
Abstract:This work investigated geopolymeric lightweight concretes based on binders composed of metakaolin with 0% and 25% fly ash, activated with 15.2% of Na2O using sodium silicate of modulus SiO2/Na2O = 1.2. Concretes of densities of 1200, 900 and 600 kg/m3 were obtained by aeration by adding aluminium powder, in some formulations lightweight aggregate of blast furnace slag was added at a ratio binder:aggregate 1:1; curing was carried out at 20 and 75 °C. The compressive and flexural strength development was monitored for up to 180 days. The strength diminished with the reduction of the density and high temperature curing accelerated strength development. The use of the slag had a positive effect on strength for 1200 kg/m3 concretes; reducing the amount of binder used. The thermal conductivity diminished from 1.65 to 0.47 W/mK for densities from 1800 to 600 kg/m3. The microstructures revealed dense cementitious matrices conformed of reaction products and unreacted metakaolin and fly ash. Energy dispersive spectroscopy and X-ray diffraction showed the formation of amorphous silicoaluminate reaction products.
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