Melt grafting of vinyltrimethoxysilane and water crosslinking of polypropylene/ethylene-propylene diene terpolymer blends |
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Authors: | Shun Zhou Zhengzhou Wang Yuan Hu |
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Affiliation: | (1) State Key Laboratory of Fire Science, University of Science and Technology of China, Anhui, 230026, People’s Republic of China;(2) School of Materials Science and Engineering, Tongji University, Shanghai, 200092, People’s Republic of China |
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Abstract: | The melt grafting of vinyltrimethoxysilane (VTMS) onto polypropylene (PP)/ethylene-propylene diene terpolymer (EPDM) blends
was studied. The effect of VTMS, EPDM and initiator concentrations on mechanical properties, melt flow index (MFI) and gel
content of the modified PP/EPDM samples were investigated. The influence of coagents, i.e. styrene and trimethylolpropane
trimethacrylate was also studied. Scanning electron microscopy (SEM) was used to observe the fractured surface of PP/EPDM
and the modified PP/EPDM blends. The VTMS grafting reaction was in situ monitored using differential scanning calorimetry
(DSC). Moreover, the thermal and crystallization behavior of VTMS-crosslinked PP/EPDM blends were studied by thermogravimetric
analysis (TG) and DSC, respectively. It had been found that the thermal stability of VTMS-crosslinked PP/EPDM was improved.
DSC measurements showed that the grafting reaction occurs from 170 to 220 °C and the crystallization temperatures increased
compared with those of the untreated PP/EPDM. |
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Keywords: | PP/EPDM Silane-crosslinking Coagent Thermal behavior Crystallization |
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