Chlorinated alcohols: II. The chlorination of oleyl alcohol |
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| Authors: | R A Grimm J E Menting A J Stirton J K Weil |
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| Affiliation: | (1) Ashland Chemical Co., 55420 Bloomington, Minnesota;(2) Eastern Regional Research Laboratory, E. Utiliz. Res. Dev. Div., ARS, USDA, 19118 Philadelphia, Pa. |
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| Abstract: | Chlorination of oleyl alcohol gives mainly 9,10-dichlorostearyl alcohol but a variety of other products are also formed. By-products
include 9(10)-(9,10-dichlorostearoxy)-10(9)-chlorostearyl alcohol (14%) and 9,10-dichlorostearyl 9,10-dichlorostearate (3–4%)
in addition to three or four less clearly defined products (12%). One group of products is apparently derived from participation
of the hydroxyl group in the chlorine addition step while the other products formed by the reaction of the hydroxyl group
with chlorine or chlorine and hydrogen chloride. |
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