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纳米含氟磷灰石涂层及其在模拟溶液中的行为
引用本文:曲海波,宋晨路,程逵,沈鸽,翁文剑,杜丕一,韩高荣. 纳米含氟磷灰石涂层及其在模拟溶液中的行为[J]. 过程工程学报, 2002, 2(4): 370-374
作者姓名:曲海波  宋晨路  程逵  沈鸽  翁文剑  杜丕一  韩高荣
作者单位:浙江大学材料科学与工程学系,浙江,杭州,310027
基金项目:国家教育部博士点基金资助项目(编号:98033536),浙江省自然科学基金资助项目(编号:598061)
摘    要:以Ca(NO3)2×4H2O和P2O5乙醇溶液为先驱体,六氟磷酸(HPF6)为氟引入剂,采用溶胶-凝胶法在钛合金基板上制备含氟羟基磷灰石涂层. 获得的涂层晶粒尺寸为120~150 nm. 实验结果表明,加入HPF6后形成的含氟磷灰石涂层在模拟体液中有良好的生物活性特性,在柠檬酸改性的磷酸缓冲溶液中表现出较好的稳定性.

关 键 词:溶胶-凝胶;含氟磷灰石;六氟磷酸;涂层
文章编号:1009-606X(2002)04-0370-05
修稿时间:2001-10-26

A Preliminary Study on in vitro Behaviors of Sol-Gel Derived Nano Fluorapatite/Hydroxyapatite Coatings
QU Hai-bo,SONG Chen-lu,CHENG Kui,SHEN Ge,WENG Wen-jian,DU Pi-yi,HAN Gao-rong. A Preliminary Study on in vitro Behaviors of Sol-Gel Derived Nano Fluorapatite/Hydroxyapatite Coatings[J]. Chinese Journal of Process Engineering, 2002, 2(4): 370-374
Authors:QU Hai-bo  SONG Chen-lu  CHENG Kui  SHEN Ge  WENG Wen-jian  DU Pi-yi  HAN Gao-rong
Abstract:A fluorapatite/hydroxyapatite coating on Ti6Al4V substrate was prepared by sol-gel technique using Ca(NO3)24H2O, P2O5, hexafluorophosporic acid (HPF6) as the starting materials and the fluorine-introducing reagent. The results show that the sol-gel derived fluorapatite/hydroxyapatite coating has a good in vitro behavior in the simulated body fluid, and has a better stability in the citric acid modified phosphate buffer solution than hydroxyapatite coating. The sol-gel derived coatings are composed of nano apatite crystallites.
Keywords:sol-gel  fluorapatite/hydroxyapatite  hexaflourophosphate  coating  
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