Phase Separation in Gelling Silica–Organic Polymer Solution: Systems Containing Poly(sodium styrenesulfonate) |
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Authors: | Kazuki Nakanishi Naohiro Soga |
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Affiliation: | Department of Industrial Chemistry, Faculty of Engineering, Kyoto University, Kyoto 606-01, Japan |
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Abstract: | Phase separation which occurs in parallel to the hydrolysis and gelation of alkoxysilane solution containing poly(sodium styrenesulfonate) (NaPSS) has been investigated. Depending on the reaction conditions, gel morphologies such as isolated pores, particle aggregates, and interconnected continuous pores from 0.1 to 100 μm long have been observed. Time-resolved light scattering of gelling solution suggested the occurrence of spinodal phase separation through the polymerization of silica and the subsequent freezing of the developing structure by sol-gel transition. The effects of reaction parameters on the periodic size are explained mainly in terms of their influence on the "chemical cooling" rate which is determined by the polymerizatica rate of silica and the solubility of NaPSS in the reacting solution. |
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Keywords: | phase separation gels silica polymers porous materials |
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