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燃煤烟气杂质影响膜法捕集CO_2的研究进展
引用本文:沙焱,杨林军.燃煤烟气杂质影响膜法捕集CO_2的研究进展[J].化工进展,2011,30(9):2069.
作者姓名:沙焱  杨林军
作者单位:东南大学能源与环境学院,江苏 南京 210096
基金项目:国家自然科学基金项目(51176034)
摘    要:膜法捕集CO2系统运行的稳定性直接制约其大规模运用,本文总结分析了其稳定性一方面受到膜自身特点,如孔径分布、孔隙率等的影响;另一方面燃煤烟气杂质对膜系统的作用也是限制其发展的要素所在,如细颗粒物会吸附沉积在膜表面或膜孔内部、水蒸气易冷凝于膜表面或在孔径内形成毛细管冷凝现象、SO2会与CO2形成竞争吸附,这些因素都会引起气体通量的变化,从而改变膜捕集系统的性能。

关 键 词:  碳捕集  细颗粒物  水蒸气  二氧化硫

Research progress of carbon dioxide capture effect of membranes affected by flue gas impurities
SHA Yan,YANG Linjun.Research progress of carbon dioxide capture effect of membranes affected by flue gas impurities[J].Chemical Industry and Engineering Progress,2011,30(9):2069.
Authors:SHA Yan  YANG Linjun
Affiliation:School of Energy and Environment,Southeast University,Nanjing 210096,Jiangsu,China
Abstract:Membranes are promising candidates for the separation of carbon dioxide from the flue gas of fossil fuel power plants.The stability of the membrane systems directly restraints its extensive application.This study analyzes the characteristics of membranes,such as pore diameter distribution and porosity,which could affect separation efficiency and stability of the system.Under real conditions,after long-term exposure in flue gas,the impurities could change the performance of membranes.The reduction of gas flu...
Keywords:membrane  carbon dioxide capture  ash particle  water vapor  sulfur dioxide  
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