Photodegradation of Selected Aromatic Constituents of Creosote in Organic Solvents |
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Authors: | Kirsi-Maarit Lehto Helge Lemmetyinen Jaakko Puhakka |
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Affiliation: | 1. Institute of Materials Chemistry;2. Institute of Water and Environmental Engineering, Tampere University of Technology , P.O. Box 541, 33101, Tampere, Finland |
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Abstract: | Polycyclic aromatic hydrocarbons (PAHs), naphthalene, phenanthrene, anthracene, and pyrene were irradiated in acetonitrile (CH3CN) and in dichloromethane (CH2Cl2) on individual PAH compounds and in the presence of other compounds. The observed photodegradation of PAHs was dependent on the structure of the compound. Anthracene and pyrene were the most photoreactive in dichloromethane: with total degradation after 0.5 h irradiation for anthracene and 1.5 h for pyrene. The decomposition of PAHs was faster in dichloromethane than in acetonitrile. |
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Keywords: | Polycyclic aromatic hydrocarbons Creosote Photodegradation |
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