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PORE-MOUTH POISONING OF NON-UNIFORM CATALYSTS
Authors:Darí  o R Ardiles  Alberto A Castro
Abstract:Impurity poisoning of a catalyst particle having a non-uniform activity distribution is analyzed. Equations that relate the position of the poison-front with time for different activity profiles are derived. It is shown that the effect of the activity distribution on the poisoning rate is apparent in the case of intraparticle-diffusion control. The performance of a non-uniform bifunctional catalyst in such conditions is also studied.
Keywords:Catalyst deactivation  Activity distribution  Pore-mouth poisoning
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