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Sorption of p-nitrophenol onto sediment in the presence of cetylpyridinium chloride and Pb(NO3)2: influence of pH
Authors:Huang Wenfei  Yao Chaoying  Jin Sujun  Ying Shanting  Shen Xueyou
Affiliation:

aDepartment of Environmental Science, Zhejiang University, Hangzhou 310028, China

bEnvironmental Science Research & Design Institute of Zhejiang Province, China

cHangzhou Vocational & Technical College, Hangzhou 310018, China

dZhejiang Institute of Standardization, Hangzhou, Zhejiang 310006, China

Abstract:pH and the presence of compounds have a great effect on the sorption of organic contaminants. In this study, batch equilibrium experiments were carried out to investigate the influence of pH on the sorption of p-nitrophenol (PNP) onto sediment in the presence of Pb(NO3)2 and cetylpyridinium chloride (CPC) cationic surfactant. Results indicated that in the multi-solute system with PNP, Pb(NO3)2 and CPC, the sorption of PNP increased with the increasing pH and the amount of sorbed PNP at equilibrium was much higher than in the single-solute system. This can be attributed to the presence of Pb(NO3)2 and CPC. It is believed that the main reason for that was the larger sorption of CPC at higher pH allowing higher sorption of PNP. The results are believed to provide a useful insight into describing the transport and fate of PNP in natural environments.
Keywords:pH   Surfactant   p-Nitrophenol   Heavy metal   Sorption
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