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Phase-equilibrium modeling in the hydrogenation of vegetable oils and derivatives |
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| Authors: | Selva Pereda Laura Rovetto Susana B. Bottini Esteban A. Brignole |
| Affiliation: | (1) Planta Piloto de Ingeniería Química (PLAPIQUI), Universidad Nacional del Sur, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Camino La Carrindanga, Km 7, C.C. 717, 8000 Bahía Blanca, Argentina |
| Abstract: | The main tool needed to carry out phase-equilibrium engineering of a given process is an adequate thermodynamic model adjusted to the range of process operating conditions of the working system. In the present work the Group Contribution with Association Equation of State (GCA-EoS) is used to model the phase behavior of reacting mixtures typical of the hydrogenation of vegetable oils and derivatives at supercritical or high-pressure conditions. |
| Keywords: | Fatty ester hydrogenolysis GCA-EoS Group Contribution with Association Equation of State thermodynamic modeling vegetable oil hydrogenation |
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