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Fabrication of egg-shell-roofed macroporous nickel films by a template-mediated electrodeposition process
Authors:Yi-Wen Chung  Jian-Hong Lee  Min-Hsiung Hon
Affiliation:a Department of Materials Science and Engineering, National Cheng Kung University, 1 Ta-Hsueh Road, Tainan 701, Taiwan, ROC
b Department of Materials Science and Engineering, National United University, Miao-Li 360, Taiwan, ROC
Abstract:Through an electrostatics-induced adsorption effect, nickel ions were found to be preferentially adsorbed onto the surface of colloidal particles at template top during the template-mediated electrodeposition process for preparing macroporous structures. This phenomenon results in the preferential reduction and growth of nickel on colloid surface on the template top, instead of filling into the channels among the colloids. After removing the template, an egg-shell-roofed macroporous nickel, consisting of macroporous film covered with monolayer of hollow spheres, can be created.
Keywords:Well-ordered macroporous film  Hollow sphere array  Template-mediated process  Electrodeposition  Nanostructure
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