Effect of particle dispersion on high rate performance of nano-sized Li4Ti5O12 anode

Nano-sized Li₄Ti₅O₁₂ powders with high dispersivity were fabricated by a sol-gel process using P123 as surfactant, which exhibited much better high rate performance towards Li⁺ insertion/extraction as compared to the densely aggregated Li₄Ti₅O₁₂ particles although the primary grain sizes of both samples were almost the same. The Li₄Ti₅O₁₂ electrode prepared from the well-dispersed nanopowders can preserve 88.6% of the capacity at 0.1 A g⁻¹ when being cycled at 1 A g⁻¹, which is obviously higher than that of the densely aggregated sample, in which only 30% capacity can be retained. By improving the dispersivity, the specific surface area of the Li₄Ti₅O₁₂ nanoparticles, hence the electrode-electrolyte contact area was increased; meanwhile, more homogeneous mixing of the active materials with carbon black was achieved. All these factors might have resulted in the better high rate performance.