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少层石墨烯对普通混凝土性能的影响
引用本文:何威,许吉航.少层石墨烯对普通混凝土性能的影响[J].硅酸盐通报,2021,40(5):1477-1488.
作者姓名:何威  许吉航
作者单位:河北省土木工程绿色建造与智能运维重点实验室,秦皇岛 066004;河北省建筑低碳清洁供热技术创新中心,秦皇岛 066004;燕山大学建筑工程与力学学院,秦皇岛 066004
基金项目:国家自然科学基金(51708403)
摘    要:为了深入研究石墨烯/混凝土复合材料,系统研究了少层石墨烯(FLGR)对普通混凝土坍落度、力学性能、抗渗性及电性能的影响,且通过扫描电子显微镜(SEM)分析了FLGR/混凝土复合材料的微观形貌,同时利用原子力显微镜(AFM)、Raman、SEM表征了FLGR.结果表明,FLGR的层数在3~6层,其D峰和G峰与单层石墨烯相...

关 键 词:少层石墨烯  混凝土  力学性能  抗渗性  电性能  水化产物
收稿时间:2021-01-10

Effect of Few-Layer Graphene on Properties of Ordinary Concrete
HE Wei,XU Jihang.Effect of Few-Layer Graphene on Properties of Ordinary Concrete[J].Bulletin of the Chinese Ceramic Society,2021,40(5):1477-1488.
Authors:HE Wei  XU Jihang
Affiliation:1. Key Laboratory of Green Construction and Intelligent Maintenance for Civil Engineering of Hebei Province, Qinhuangdao 066004, China; 2. Low-Carbon and Clean Building Heating Technology Innovation Center of Hebei Province, Qinhuangdao 066004, China; 3. College of Civil Engineering and Mechanics, Yanshan University, Qinhuangdao 066004, China
Abstract:To further study graphene/concrete composites, the effect of few-layer graphene (FLGR) on the slump, mechanical properties, impermeability and electrical properties of ordinary concrete was systematically studied, and SEM was used to analyze the microstructure of FLGR/concrete composites. Meanwhile, AFM, Raman and SEM were used to characterize FLGR. The results show that the layer number of FLGR is between 3 layers and 6 layers, and the D and G peaks of FLGR are red-shifted compared with that of monolayer graphene. FLGR is an ultra-thin lamellar structure with wrinkles on the surface and it has a very tight microstructure. The addition of FLGR reduces the slump of concrete, and 28 d compressive strength of concrete increases by 15.08%, 28 d flexural strength increases by 35.03%, the height of penetration decreases by 57%. FLGR has the function of increasing the conductivity of concrete, and FLGR/concrete composites present negative temperature coefficient effect. FLGR can better promote the connection between hydration products, act the part of bridging ettringite and C-S-H gel to fill cracks and pores in cement matrix.
Keywords:few-layer graphene  concrete  mechanical property  impermeability  electrical property  hydration product  
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