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煅烧温度对水泥熟料矿物相含量及形貌影响的Rietveld法研究
引用本文:杨欢,齐砚勇,高宇蕾,邓磊,李诗颖. 煅烧温度对水泥熟料矿物相含量及形貌影响的Rietveld法研究[J]. 硅酸盐通报, 2021, 40(9): 2871-2876
作者姓名:杨欢  齐砚勇  高宇蕾  邓磊  李诗颖
作者单位:西南科技大学材料科学与工程学院,绵阳 621010;绵阳职业技术学院材料与建造学院,绵阳 621000;四川峨胜水泥集团股份有限公司,乐山 614222;四川利森建材集团有限公司,德阳 618400
摘    要:为了探究煅烧温度对水泥熟料矿物相的影响,采用XRD分析法、Rietveld法以及岩相法,对不同煅烧温度下得到的熟料矿物相进行定性、定量以及形貌分析.研究结果表明:采用Rietveld法可快速、准确测得熟料中各矿物相的相对含量;通过Rietveld法计算得到的矿物相含量可明显看出,煅烧温度对熟料中各矿物相的含量有直接影响...

关 键 词:Rietveld法  岩相  煅烧温度  硅酸盐水泥熟料  矿物相含量
收稿时间:2021-03-26

Influence of Calcination Temperature on Mineral Phase Content and Morphology of Cement Clinker by Rietveld Method
YANG Huan,QI Yanyong,GAO Yulei,DENG Lei,LI Shiying. Influence of Calcination Temperature on Mineral Phase Content and Morphology of Cement Clinker by Rietveld Method[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(9): 2871-2876
Authors:YANG Huan  QI Yanyong  GAO Yulei  DENG Lei  LI Shiying
Affiliation:1. School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China;2. School of Materials and Construction, Mianyang Polytechnic, Mianyang 621000, China;3. Sichuan Esheng Cement Group Co., Ltd., Leshan 614222, China;4. Sichuan Lisen Building Materials Group Co., Ltd., Deyang 618400, China
Abstract:In order to explore the influence of calcination temperature on the mineral phase of cement clinker, the clinker was analyzed qualitatively, quantitatively and morphologically by XRD, Rietveld and lithofacies method. The results show that Rietveld method can be used to measure the relative content of each mineral phase in the clinker quickly and accurately. According to the content of mineral phase calculated by Rietveld method, it can be seen that calcination temperature has a direct effect on the content of mineral phase in the clinker, especialy C3S and C2S. The results of mineral phase content obtained by Rietveld method are close to those obtained by Bague algorithm, but the content of C3A obtained by fitting is lower. This is due to the rapid cooling of clinker which makes C3A exist as glass phase. With the increase of calcination temperature, the crystal nucleation and development are more perfect, and the clinker shows better morphology.
Keywords:Rietveld method  lithofacies  calcination temperature  Portland cement clinker  mineral phase content  
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