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纳米二氧化硅对白水泥基3D打印材料结构变形、流变及力学性能的影响
引用本文:金源,徐嘉宾,孙登田,陈明旭,黄永波,芦令超,程新. 纳米二氧化硅对白水泥基3D打印材料结构变形、流变及力学性能的影响[J]. 硅酸盐通报, 2021, 40(6): 1855-1862
作者姓名:金源  徐嘉宾  孙登田  陈明旭  黄永波  芦令超  程新
作者单位:济南大学,山东省建筑材料制备与测试技术重点实验室,济南250022;山东省乡镇企业建材质量监督检验中心,泰安271000
基金项目:国家自然科学基金(52072147)
摘    要:与传统建筑材料相比,3 D打印建筑材料的结构建立对打印材料的流变性能具有更高的要求.通过引入纳米二氧化硅来调控白水泥基3D打印材料的流变性能,旨在稳定打印后的浆体结构和改善材料的力学性能.研究表明,纳米二氧化硅的掺入可以明显缩短浆体的凝结时间,改善其早期力学性能.同时,纳米二氧化硅的掺入能够提高浆体的屈服应力和弹性模量...

关 键 词:白水泥  纳米二氧化硅  3D打印  流变性能  力学性能  凝结时间  结构变形
收稿时间:2021-04-01

Effect of Nano-Silica on Structural Deformation,Rheological and Mechanical Properties of 3D Printed White Portland Cement-Based Materials
JIN Yuan,XU Jiabin,SUN Dengtian,CHEN Mingxu,HUANG Yongbo,LU Lingchao,CHENG Xin. Effect of Nano-Silica on Structural Deformation,Rheological and Mechanical Properties of 3D Printed White Portland Cement-Based Materials[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(6): 1855-1862
Authors:JIN Yuan  XU Jiabin  SUN Dengtian  CHEN Mingxu  HUANG Yongbo  LU Lingchao  CHENG Xin
Affiliation:1. Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, University of Jinan, Jinan 250022, China; 2. Shandong Provincial Township Enterprise Quality Supervision and Inspection Centre of Building Materials, Taian 271000, China
Abstract:Compared with the traditional building materials, the printed structure build-up of 3D printed building materials proposes higher requirements on the rheological properties. The nano-silica was introduced to control the rheological properties of 3D printed white Portland cement-based materials, aiming to stabilize the paste structure and improve the mechanical properties. The experimental results show that the nano-silica shortens the setting time significantly, and improves the early mechanical properties of 3D printed white Portland cement-based materials. Meanwhile, the addition of nano-silica in 3D printed white Portland cement-based materials improves the yield stress and elastic modulus, which is conducive to resist its own gravity and reduce printed structural deformation. In addition, the 3 d compressive strength and flexural strength reach up to 46.9 MPa and 6.1 MPa, respectively, when the dosage of nano-silica reaches 0.5% (mass fraction). Based on the correlation of multiple rheological parameters, the dynamic yield behaviors present little influence on the deformation of the 3D printed structure, while the static yield stress presents the reverse phenomenon, which influences the structural deformation obviously. In conclusion, the introduction of nano-silica into the 3D printed white Portland cement-based materials can well control the rheological properties, and improve the printed structures and early mechanical properties.
Keywords:white Portland cement  nano-silica  3D printing  rheological property  mechanical property  setting time  structural deformation  
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