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铝酸三钙和碳酸钙对硅酸盐水泥早期力学强度及凝结时间的协同作用研究
引用本文:严子伟,刘黎,孙晋峰,卢豹,祖庆贺,臧军,李德标,侯贵华. 铝酸三钙和碳酸钙对硅酸盐水泥早期力学强度及凝结时间的协同作用研究[J]. 硅酸盐通报, 2021, 40(5): 1470-1476
作者姓名:严子伟  刘黎  孙晋峰  卢豹  祖庆贺  臧军  李德标  侯贵华
作者单位:江苏大学材料科学与工程学院,镇江 212013;盐城工学院,江苏省新型环保重点实验室,盐城 224051;徐州中联混凝土有限公司,徐州 221100;盐城市荣立新型建材有限公司,盐城 224051
基金项目:江苏省科技计划(BZ2020012)
摘    要:本文研究了协同掺加铝酸三钙(C3 A)和碳酸钙(CaCO3)对硅酸盐水泥早期水化及硬化性能的影响.用X射线衍射(XRD)、热重分析(TG)、扫描电子显微镜(SEM)等技术分析水化产物及显微结构.结果表明,协同掺加C3 A和CaCO3会显著提高硅酸盐水泥的早期力学强度.当硅酸盐水泥中掺加15%(质量分数,下同)的C3 A...

关 键 词:凝结时间  力学性能  铝酸三钙  碳酸钙  协同作用  碳铝酸钙
收稿时间:2021-01-13

Synergistic Effect of Tricalcium Aluminate and Calcium Carbonate on Early Mechanical Strength and Setting Time of Portland Cement
YAN Ziwei,LIU Li,SUN Jinfeng,LU Bao,ZU Qinghe,ZANG Jun,LI Debiao,HOU Guihua. Synergistic Effect of Tricalcium Aluminate and Calcium Carbonate on Early Mechanical Strength and Setting Time of Portland Cement[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(5): 1470-1476
Authors:YAN Ziwei  LIU Li  SUN Jinfeng  LU Bao  ZU Qinghe  ZANG Jun  LI Debiao  HOU Guihua
Affiliation:1. College of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China; 2. Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng 224051, China; 3. China United Concrete Xuzhou Co., Ltd., Xuzhou 221100, China; 4. Yancheng Rongli New Building Materials Co., Ltd., Yancheng 224051, China
Abstract:In this paper, the synergistic effect of tricalcium aluminate (C3A) and calcium carbonate (CaCO3) on the early hydration and hardening properties of Portland cement was studied. Then a series of methods including X-ray diffraction (XRD), thermogravimetric analysis (TG) and scanning electron microscopy (SEM) were adopted to analyze the hydrates and microstructures. Results indicate that the simultaneous addition of C3A and CaCO3 effectively boosts the mechanical strength of the Portland cement mortar and the content of C3A and CaCO3 are 15% (mass fraction, the same below) and 5.6% respectively presented the best mechanical performance. Compared to the reference mortar, this combination increases the compressive strength by 28.8%, 55.7%, 26.8% at 3 d, 7 d and 14 d, respectively. It is inferred that the simultaneous addition of C3A and CaCO3 stimulates the formation of calcium carboaluminate, which benefits the early mechanical strength development.
Keywords:setting time  mechanical property  tricalcium aluminate  calcium carbonate  synergistic effect  calcium carboaluminate  
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