| 负载型金属配合物催化硅氢加成反应研究进展 |
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| 引用本文： | 赵建波,孙雨安,张宁,杨浩.负载型金属配合物催化硅氢加成反应研究进展[J].工业催化,2005,13(12):10-13. |
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| 作者姓名： | 赵建波 孙雨安 张宁 杨浩 |
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| 作者单位： | 郑州轻工业学院材料与化工学院,河南,郑州,450002;南昌大学化学系,江西,南昌,330047 |
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| 基金项目： | 郑州轻工业学院青年基金资助项目 |
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| 摘 要： | 硅氢加成反应是有机硅化学中制备含Si-C化合物的一类重要反应。综述了硅氢加成反应中负载型金属配合物催化剂的种类、催化性能及催化机理，并展望了此类反应的研究前景，表明探索价廉高效的硅氢加成催化体系将是这一领域的主要研究方向。
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| 关 键 词： | 负载型催化剂 金属配合物 硅氢加成 催化机理 |
| 文章编号： | 1008-1143(2005)12-0010-04 |
| 收稿时间： | 2005-05-16 |
| 修稿时间： | 2005-07-22 |
Advances in supported metal complex catalysts for hydrosilylation |
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| ZHAO Jian-bo,SUN Yu-an,ZHANG Ning,YANG Hao.Advances in supported metal complex catalysts for hydrosilylation[J].Industrial Catalysis,2005,13(12):10-13. |
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| Authors: | ZHAO Jian-bo SUN Yu-an ZHANG Ning YANG Hao |
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| Affiliation: | 1.College of Material and Chemical Engineering, Zhengzhou Institute of Light Industry,; Zhengzhou 450002,China; 2.Department of Chemistry, Nanchang University, Nanchang 330047, China |
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| Abstract: | Hydrosilylation catalyzed by metal complex is one of the most important Si-C bond formation reactions in organosilicon chemistry. The sorts of hydrosilylation catalysts, their catalytic properties and mechanism for hydrosilylation reaction catalyzed by supported metal complex were reviewed. The prospects for catalytic hydrosilylation were outlined, too. |
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| Keywords: | supported metal complex catalyst hydrosilylation catalytic reaction mechanism |
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