| H_4SiW_（12）O_（40）/ZrO_2-Al_2O_3催化合成丁酮1,2-丙二醇缩酮 |
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| 引用本文： | 杨水金,王强,段国滨,黄涛. H_4SiW_（12）O_（40）/ZrO_2-Al_2O_3催化合成丁酮1,2-丙二醇缩酮[J]. 徐州工程学院学报, 2012, 0(3): 22-26 |
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| 作者姓名： | 杨水金 王强 段国滨 黄涛 |
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| 作者单位： | 湖北师范学院化学与环境工程学院,湖北黄石435002 |
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| 基金项目： | 湖北省自然科学基金项目（2005ABA053） |
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| 摘 要： | 采用浸渍法制备ZrO2-Al2O3复合载体负载硅钨酸催化剂H4SiW12O40/ZrO2-Al2O3,并通过FT-IR、XRD对其进行了表征.以H4SiW12O40/ZrO2-Al2O3为催化剂催化合成丁酮1,2-丙二醇缩酮.系统地研究了各种因素对收率的影响.结果表明：H4SiW12O40/ZrO2-Al2O3催化剂是合成丁酮1,2-丙二醇缩酮的良好催化剂,固定丁酮物质的量为0.20mol,丁酮与1,2-丙二醇质量比为1：1.5,带水剂环己烷的用量为8mL,反应时间60min,催化剂的用量占反应物总质量的1.5%的优化条件下,产品的收率可达78.1%.
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| 关 键 词： | 丁酮1,2-丙二醇缩酮 H4SiW12O40/ZrO2-Al2O3 催化 |
Catalytic Synthesis of Butanone 1,2-Propanedioi Ketal with H4 SiW12 O40/ZrO2-Al2O3 |
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| YANG Shui-jin,WANG Qiang,DUAN Guo-bin,HUANG Tao. Catalytic Synthesis of Butanone 1,2-Propanedioi Ketal with H4 SiW12 O40/ZrO2-Al2O3[J]. Journal of Xuzhou Istitute of Technology, 2012, 0(3): 22-26 |
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| Authors: | YANG Shui-jin WANG Qiang DUAN Guo-bin HUANG Tao |
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| Affiliation: | (College of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002, China) |
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| Abstract: | H4SiW12 O40/ZrO2-Al2O3 was prepared by impregnation, and characterized by FT-IR and XRD. Catalytic activity of H4SiW12 O40/ZrO2-Al2O3 was evaluated by the synthesis of cyclohexanone 1,2- propanediol ketal. The factors influencing the synthesis were discussed. The optimum conditions are. mo- lar ratio of butanone to 1,2-propanediol glycol is 1 ： 1.5, the quantity of catalyst is equal to 1.5 % of feed stocks, the volume of cyclohexane as the water-carrying agent is 8mL, and the reaction time is 60 min. H4SiW12 O40/ZrO2-Al2O3 is an excellent catalyst for synthesizing butanone 1, 2-propanediol ketal and its yield can be up to 78.1%. |
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| Keywords: | Butanone 1, 2-propanediol ketal H4 SiW12 O40/ZrO2-Al2O3 catalysis |
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