| 整体型催化剂上甲烷自热氧化制合成气 |
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| 引用本文： | 王亚权,侯永江,齐随涛. 整体型催化剂上甲烷自热氧化制合成气[J]. 燃烧科学与技术, 2001, 7(2): 105-109 |
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| 作者姓名： | 王亚权 侯永江 齐随涛 |
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| 作者单位： | 天津大学化工学院, |
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| 基金项目： | 天津市自然科学基金资助项目(983603411)。 |
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| 摘 要： | 用镍金属制备了一整体催化剂并与负载铑和铂比较了甲烷氧化制合成气的性能。结果表明，镍金属催化剂上甲烷转化率、H2和CO的选择性与铑催化剂相当，而且稳定性非常好。反应中加入H2O和CO2的实验表明，产物中H2／CO的比例可以直接调节。
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| 关 键 词： | 甲烷 氧化 合成气 催化剂 |
| 文章编号： | 1006-8740(2001)02-0105-05 |
| 修稿时间： | 1999-11-12 |
Partial Oxidation ofMethane to Syngas Autothermally over Monolithic Catalysts |
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| WANG Ya-quan,HOU Yong-jiang,QI Sui-tao. Partial Oxidation ofMethane to Syngas Autothermally over Monolithic Catalysts[J]. Journal of Combustion Science and Technology, 2001, 7(2): 105-109 |
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| Authors: | WANG Ya-quan HOU Yong-jiang QI Sui-tao |
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| Abstract: | A monolithic Ni metal catalyst was prepared and its performace in the partial oxidation of methane to syngas was compared with that of supported Rh and Pt catalysts.It was shown that the Ni metal catalyst gave the similar methane conversion and selectivity to H 2 and CO as supported Ni and Rh catalysts,but had excellent stability.The results with H 2O and CO addition in the reaction indicate that H 2/CO ratio in the products can be adjusted directly in the reaction. |
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| Keywords: | Ni monolith methane partial oxidation syngas |
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