|
|||||
|
|
Autoxidation Chemistry: Bridging the Gap Between Homogeneous Radical Chemistry and (Heterogeneous) Catalysis |
|
| Authors: | Ive Hermans Jozef Peeters Pierre A. Jacobs |
| Affiliation: | 1. Department of Microbial and Molecular Systems (M2S), Centre for Surface Chemistry and Catalysis, K. U. Leuven, Kasteelpark Arenberg 23, 3001, Leuven, Belgium 2. Institute for Chemical and Bioengineering, ETH Zürich, H?nggerberg, HCI, Wolfgang-Pauli-Str. 10, 8093, Zurich, Switzerland 3. Department of Chemistry, K. U. Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium |
| Abstract: | During the autoxidation of cyclohexane, abstraction of the αH-atom of the hydroperoxide product by chain-carrying peroxyl radicals produces both the desired alcohol and ketone products, as well as the majority of by-products. Rationalizing the impact of this reaction, one should aim for a (catalytic) destruction of this hydroperoxide without the intervention of peroxyl chain-carriers. Starting from these new insights in the molecular mechanism, attempts for rational catalyst design are initiated. |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ | |