Ionic conduction in poly(vinyl chloride)/poly(ethyl methacrylate)-based polymer blend electrolytes complexed with different lithium salts |
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Authors: | S. Rajendran M. Ramesh Prabhu M. Usha Rani |
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Affiliation: | aDepartment of Physics, Alagappa University, Karaikudi, 630 003, India |
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Abstract: | Poly(vinyl chloride)/poly(ethyl methacrylate)-based polymer blend electrolytes comprising propylene carbonate as a plasticizer and a lithium salt LiX (X = BF4−, ClO4−, CF3SO3−) are prepared by a solvent casting technique. The electrolytes are subjected to characterization by ionic conductivity, X-ray diffraction, Fourier transform infrared spectroscopy and thermogravimetic/differential thermal analysis. The electrolytes that contain LiBF4 exhibit maximum conductivity and are thermally stable up to 254 °C. |
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Keywords: | Polymer electrolyte Ionic conductivity Impedance studies Solid-state battery Thermal stability Lithium salt |
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