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Ionic conduction in poly(vinyl chloride)/poly(ethyl methacrylate)-based polymer blend electrolytes complexed with different lithium salts
Authors:S. Rajendran   M. Ramesh Prabhu  M. Usha Rani
Affiliation:

aDepartment of Physics, Alagappa University, Karaikudi, 630 003, India

Abstract:Poly(vinyl chloride)/poly(ethyl methacrylate)-based polymer blend electrolytes comprising propylene carbonate as a plasticizer and a lithium salt LiX (X = BF4, ClO4, CF3SO3) are prepared by a solvent casting technique. The electrolytes are subjected to characterization by ionic conductivity, X-ray diffraction, Fourier transform infrared spectroscopy and thermogravimetic/differential thermal analysis. The electrolytes that contain LiBF4 exhibit maximum conductivity and are thermally stable up to 254 °C.
Keywords:Polymer electrolyte   Ionic conductivity   Impedance studies   Solid-state battery   Thermal stability   Lithium salt
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