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PZT液相包裹法合成机理研究
引用本文:朱为民 李承恩. PZT液相包裹法合成机理研究[J]. 无机材料学报, 1996, 11(1): 45-50
作者姓名:朱为民 李承恩
作者单位:中国科学院上海硅酸盐研究所
摘    要:为了对PZT材料合成机理进行研究,本文用液相包裹法对同一组成的PZT配方,以二组不同的活性中间体与液相组分进行了前驱体的制备.初步揭示了它们的合成过程及机理,并与团相法相比较,解释了液相包裹法合成温度低于固相法的原因,提出了在制备功能陶瓷粉体时,应选择化学活性接近的原料相匹配,以合成制得纯净的单一相的观点.

关 键 词:合成机理 液相包裹法 前驱体 锆钛酸铅 压电陶瓷

Mechanism of PZT Synthesis by Liquid-Phase Coating Method
Zhu Weimin ,Li Chengen ,Xue Junmin ,Ni Huanyao. Mechanism of PZT Synthesis by Liquid-Phase Coating Method[J]. Journal of Inorganic Materials, 1996, 11(1): 45-50
Authors:Zhu Weimin   Li Chengen   Xue Junmin   Ni Huanyao
Abstract:To study the mechanism of PZT powder synthesis, two kinds of precursors with the same PZT composition were prepared by means of liquid-phase coating method starting with two kinds of liquid phases and intermediate solid phases with different reaction activities. The reaction process and synthesis mechanism were revealed preliminarily and the reasons that synthesis temperature for this method is lower than that for solid phase method were also explained. It was pointed out that the starting materials with close chemical activities should be used in order to obtain single phase materials.
Keywords:syntheisis mechanism  liquid-phase coating  precursor  activity
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