Phosphorous Enrichment in Molten Adjusted Converter Slag：Part II Enrichment Behavior of Phosphorus in CaO-SiO_2-FeO_x-P_2O_5 Molten Slag

 The enrichment behavior of phosphorus in CaO-SiO2-FeOx-P2O5 slag was studied by making an investigation on the distribution of phosphorous content in the CaO-SiO2-FeOx-P2O5 molten slag. The research results showed that the 2CaO·SiO2 solid particles existing in molten slag were the condensation sites for the phosphorus enrichment. The enrichment process of phosphorus in the molten slag can be recognized as three substeps: mass transfer of phosphorus from bulk slag to the surface of 2CaO·SiO2 particle, superficial solid solution reaction of phosphorus around the 2CaO·SiO2 particle, and diffusion of phosphorus through the product layer of 2CaO·SiO2-3CaO·P2O5 solid solution to the inner of 2CaO·SiO2 particle. Moreover, higher temperature is favorable to the phosphorous enrichment from molten bulk slag to the 2CaO·SiO2 particles.