Physicochemical properties of talc ore from three deposits of Lamal Pougue area (Yaounde Pan-African Belt, Cameroon), in relation to industrial uses

Three talc deposits were discovered at Ngoung, Lamal Pougue and Bibodi Lamal (Cameroon). They derived from ultramafic rocks and are enclosed in a Pan-African garnet and muscovite-bearing mica schist of the Yaoundé series. The physico-chemical properties of these talc deposits have been investigated by different techniques including Scanning Electron and Transmission Microscopy (SEM and TEM), chemical analyses, X-ray diffraction (XRD), infrared spectroscopy, particle size analysis by laser diffraction and low temperature gas absorption–desorption. The mineralogical composition deduced from XRD is wide (talc + chlorite + tremolite ± anthophyllite ± chromite ±serpentine ± brucite ± magnesite ± dolomite), but due to the high talc contents (≈ 90%) the samples are close to monomineralic. SEM studies reveal that all talc deposits comprise bundles of platy talc and a few prismatic crystals of amphiboles and other contaminating minerals. Laser diffraction confirms the coarse particle size of the talc crystals. Mode values are as high as 105–170 μm (except two samples displaying 76 and 42 μm) and d50 ranges from 107 to 25 μm. The values of specific surface area measured by BET and t-plot methods range from 1 to 6 m²/g and are correlated with external specific surface area measured by laser diffraction. Discrepancies from the trend are due to the semi-crystalline texture of the samples and mostly to intra-crystalline structural defects revealed by TEM observations. In infrared spectra, specific absorption bands are distinguished for talc, chlorite, tremolite, carbonates, serpentine, brucite and water. Occasional substitutions in minerals led to a shift in some absorption bands. The chemical composition criteria important for most of the industrial applications such as ceramics and pharmaceutics are closely complied with in untreated samples from these deposits. In summary, high talc proportions, chemical compositions, platy morphology and coarse grain size of its crystals lead to the conclusion that the studied deposits are economically attractive. The data set of the present work is an important tool for choosing the beneficiation methods for specific applications.