Thermal conductivity of a chemically reacting ternary gas mixture |
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Authors: | M. I. Verba V. D. Portnov |
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Affiliation: | (1) Power Engineering Institute, Moscow |
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Abstract: | On the basis of the thermodynamics of irreversible processes, an expression is derived for the thermal conductivity of a chemically reacting gas mixture.Notation xi molar fraction of i-th component - Ju energy flux - ci mass fraction of i-th component - Jq heat flux - Ji mass flux of i-th component - T absolute temperature - i molar chemical potential of i-th component - Lik, Luu, Lui phenomenological coefficients, associated respectively with the transfer of mass and energy and with the superimposed effects - Xu and Xk thermodynamic forces associated with the mass and energy fluxes - hi enthalpy of i-th component - S entropy of i-th component - Dij diffusion coefficient of a multicomponent mixture - DiT thermodiffusion coefficient of i-th component in a multicomponent system - 0(O, p) chemical potential in standard state - density - h number density of mixture particles - hj number density of particles of i-th component - mi molecular weigh of i-th component - p pressure of mixture - vi specific volume of i-th component - H heat of reaction - r number of component of mixture - R gas constant - dt thermodiffusion coefficient of a binary mixture |
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