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柴油非临氢降凝催化剂的研制与评价
引用本文:宋毅,刘洁,翟玉春. 柴油非临氢降凝催化剂的研制与评价[J]. 辽宁石油化工大学学报, 2007, 27(4): 17-20
作者姓名:宋毅  刘洁  翟玉春
作者单位:东北大学,辽宁沈阳,110006;辽宁石油化工大学石油化工学院,辽宁抚顺,113001
摘    要:以ZSM -5 为主体, 加入一定量的自制BCM 沸石, 采用水热合成法合成新型柴油非临氢降凝催化剂, 以催化裂化柴油和常三线馏分油为原料对其反应性能进行评价。结果表明, 本降凝催化剂具有明显的降凝效果, 当反应温度为340 ℃, 空速为1 h -1 时, 凝点降幅为62 ℃左右, 且液体产品收率高, 均在95 %以上。本降凝催化剂生产的柴油十六烷值高, 硫、氮含量低, 凝点低, 基本满足产品调和出厂的质量要求。

关 键 词:非临氢  降凝  催化剂
文章编号:1672-6952(2007)04-0017-04
收稿时间:2007-07-10
修稿时间:2007-09-17

Preparation and Evaluation of Catalyst for Non-Hydrogen Dewaxing
SONG Yi,LIU Jie,ZAI Yu-chun. Preparation and Evaluation of Catalyst for Non-Hydrogen Dewaxing[J]. Journal of Liaoning University of Petroleum & Chemical Technology, 2007, 27(4): 17-20
Authors:SONG Yi  LIU Jie  ZAI Yu-chun
Affiliation:1.Northeastern University , Sheny ang Liaoning 110006 , P .R .China;2.School o f Petrochemical Technology ,Liaoning University of Petroleum &Chemical Technology , Fushun Liaoning 113001 , P .R .China
Abstract:A new catalyst for non-hydrogen-dewaxing was prepared by hydrothermal method,using ZSM-5 as the principal component and then adding self-made BCM zeolites.Its catalytic performance was evaluated using catalytic cracked diesel fuel and AGO NO.3 as feed stock.The results show that catalyst has obvious de-waxing effect.The pour point can be reduced by 62 ℃,and higher liquor yield(>95%) were obtained at the temperature of 340 ℃ and space velocity of 1 h-1.The diesel oil produced using the catalyst shows higher cetane number index,lower content of sulfur and nitrogen,and lower pour point,can meet the quality requirements of product blending.
Keywords:Non-hydrogen   Dewaxing    Catalyst
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