| 四氯乙烷在烯烃聚合催化剂中的作用研究 |
| |
| 引用本文： | 饶国瑛,董永升,杨载松,杜向东,栗同林.四氯乙烷在烯烃聚合催化剂中的作用研究[J].石油化工,2002,31(9):734-736. |
| |
| 作者姓名： | 饶国瑛 董永升 杨载松 杜向东 栗同林 |
| |
| 作者单位： | 1. 北京化工大学,理学院,北京,100029
2. 北京燕山石化研究院,北京,102500 |
| |
| 摘 要： | 用FT-IR法研究了四氯乙烷在烯烃聚合催化剂体系中的作用。结果表明,由于四氯乙烷的加入使催化剂中甲基吡咯和三乙基铝的氢键打开形成各自游离态分子,消除由于氢键所造成的分子间作用力和空间位阻,有利于组分间配位。
|
| 关 键 词： | 烯烃聚合 四氯乙烷 红外光谱 氢键 |
| 文章编号： | 1000-8144(2002)09-0734-03 |
| 修稿时间： | 2002年1月14日 |
Effect of Cellon in the Catalyst System on Olefin Polymerization |
| |
| RAO Guo-ying ,DONG Yong-sheng ,YANG Zai-song ,DU Xiang-dong ,LI Tong-lin.Effect of Cellon in the Catalyst System on Olefin Polymerization[J].Petrochemical Technology,2002,31(9):734-736. |
| |
| Authors: | RAO Guo-ying DONG Yong-sheng YANG Zai-song DU Xiang-dong LI Tong-lin |
| |
| Affiliation: | RAO Guo-ying 1,DONG Yong-sheng 1,YANG Zai-song 1,DU Xiang-dong 2,LI Tong-lin 2 |
| |
| Abstract: | Effect of cellon existing in the catalyst system on olefin polymerization was examined by Fourier transform infrared spectroscopy (FT-IR).The results showed that cellon in the system caused the hydrogen bonds of methyl pyrrole and triethyl aluminum in the system to break into the corresponding unbound states,thereby eliminating the intermolecular forces and spatial hindrance formed by hydrogen bonds,and thus facilitating coordination between the components. |
| |
| Keywords: | olefin polymerization cellon FT-IR hydrogen bond |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
