Eu(OTf)3-catalyzed oxidation of 5-alkylidene-4,5-dihydrofurans: A new approach to functionalized furylhydroperoxides |
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Affiliation: | 1. Department of Chemistry, Kwangwoon University, Seoul 139-701, Republic of Korea;2. Department of Chemistry, Yonsei University, Seoul 120-749, Republic of Korea |
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Abstract: | Here reported is an unusual catalytic ability of Eu(OTf)3 in the oxidative conversion of 5-alkylidene-4,5-dihydrofuran derivatives in the corresponding furylhydroperoxides with tert-butyl hydroperoxide. Furthermore, an enantioselective process of disproportionation of furylhydroperoxides has been highlighted in the presence of the Jacobsen’s catalyst (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride. |
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