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An integrated low temperature approach to highly photoactive nanocrystalline mesostructured titania
Affiliation:1. Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, No. 220#, Handan Road, Shanghai 200433, PR China;2. Department of Chemistry, Shanghai Normal University, Shanghai 200234, PR China;1. Key Laboratory of Organic Synthesis of Jiangsu Province, Department of Chemistry and Chemical Engineering, Dushu Lake Campus, Soochow University, Suzhou, Jiangsu 215123, PR China;2. Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, 398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu 215123, PR China;3. Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou, Jiangsu 215123, PR China;4. SunaTech Inc., Suzhou Industrial Park, Suzhou, Jiangsu 215123, PR China;1. Yangtze Delta Region Institute (Huzhou) & Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Huzhou 313000, China;2. College of Architecture and Environment, Sichuan University, Chengdu 610065, China;1. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Hubei Key Lab on Organic and Polymeric Optoelectronic Materials, Department of Chemistry, Wuhan University, Wuhan 430072, People’s Republic of China;2. Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, People’s Republic of China;1. School of Physics and Materials Science, Anhui University, Hefei 230601, PR China;2. Key laboratory of Materials Modification by Laser, Ion and Electron Beams (Dalian University of Technology), Ministry of Education, Dalian 116024, PR China;3. College of Chemistry & Chemical Engineering, Anhui University, Hefei 230601, PR China;1. Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory of Function Materials for Molecule & Structure Construction, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, 100083, PR China;2. Beijing National Day School, Beijing, 100039, PR China
Abstract:A new type of nanocrystalline mesostructured TiO2 (NMT) predominantly in the anatase phase with a high specific surface area up to 269 m2 g−1 was prepared by a novel integrated nonhydrolytic sol–gel/UV-illumination technique at low temperature. During the gaseous phase photocatalytic degradation of acetone, the material exhibited excellent photoactivity, much higher than commercial Degussa P-25, which closely related to the markedly enhanced crystallization degree and the beneficial formation of surface Ti–OH groups on the NMT sample during the post UV-illumination process.
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