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Hydrogen generation from hydrolysis of alkaline sodium borohydride solution using Pt/C catalyst
Affiliation:1. College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, PR China;2. PEMFC Key Materials and Technology Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, PR China;1. College of Resources and Environment, Qingdao Agricultural University, 700 Changcheng Road, Qingdao, 266109, China;2. College of Materials Science and Technology, Qingdao University of Science & Technology, 53 Zhengzhou Road, Qingdao, 266042, China;3. College of Chemical Engineering, Qingdao University of Science & Technology, 53 Zhengzhou Road, Qingdao, 266042, China;1. Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin 541004, PR China;2. School of Material Science & Engineering, Guilin University of Electronic Technology, Guilin 541004, PR China;3. Advanced Research Centre, Central South University, Changsha 410083, PR China;4. Institute of Urban Underground Space and Energy Studies, The Chinese University of Hong Kong, Shenzhen 518172, PR China
Abstract:Hydrogen generation from catalytic hydrolysis of aqueous NaOH-stabilized sodium borohydride solutions was investigated using platinum catalysts dispersed on active carbon, carbon black, and alumina supports. The Pt/C catalyst shows high catalytic activity due to the large BET surface area of active carbon support. The investigations on the effects of Pt loading and calcination temperature on the performance of Pt/C catalyst were also performed. After filtration from the reaction medium and rinsing with water, the used catalyst was re-evaluated and almost the same catalytic activities as fresh catalyst were obtained during several cycles.
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