| 环脲硝胺类含能化合物的合成及性能研究进展 |
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| 引用本文： | 马丛明,刘祖亮,姚其正.环脲硝胺类含能化合物的合成及性能研究进展[J].含能材料,2014,22(2):263-269. |
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| 作者姓名： | 马丛明 刘祖亮 姚其正 |
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| 作者单位： | 南京理工大学化工学院, 江苏 南京 210094;南京理工大学化工学院, 江苏 南京 210094;南京理工大学化工学院, 江苏 南京 210094 |
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| 摘 要： | 综述了环脲硝胺系列含能化合物的合成研究现状,指出该类化合物的合成方法主要有两种,即脲缩合-硝化法和小分子缩合-硝化法;与其他含能化合物相比,N-二硝基取代的环脲硝胺类化合物密度大,爆速高,水解稳定性差,初步讨论了形成这些特点的原因,揭示了这类化合物在含能材料领域具有不可忽视的作用与地位。
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| 关 键 词： | 有机化学 环脲硝胺 含能材料 合成 性能 |
| 收稿时间： | 2013/4/10 0:00:00 |
| 修稿时间： | 2013/7/10 0:00:00 |
Progress in Synthesis and Performance of Cyclourea Nitro-amine Energetic Compounds |
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| MA Cong-ming,LIU Zu-liang and YAO Qi-zheng.Progress in Synthesis and Performance of Cyclourea Nitro-amine Energetic Compounds[J].Chinese Journal of Energetic Materials,2014,22(2):263-269. |
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| Authors: | MA Cong-ming LIU Zu-liang and YAO Qi-zheng |
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| Affiliation: | School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China;School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China;School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China |
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| Abstract: | The synthesis of cyclourea nitro-amine energetic compounds is reviewed. Two synthetic methods of cyclourea nitro-amine derivatives through urea condensation-nitration method or small molecule condensation-nitration method are summarized. Compared to other energetic compounds, the characteristics of N-dinitro-substituted cyclourea nitro-amine derivatives have high density, high detonation velocity and poor hydrolytic stability, and possible reasons for these performances are preliminarily discussed. Their importance in energetic materials are revealed. |
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| Keywords: | organic chemistry cyclourea nitro-amine energetic compounds synthesis performance |
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