| 纳米二氧化硅／MC尼龙6原位复合材料非等温结晶动力学 |
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| 引用本文： | 林毅利,林志勇,钱浩,LAN Xin-ren.纳米二氧化硅／MC尼龙6原位复合材料非等温结晶动力学[J].化学工程与装备,2009(1):13-17. |
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| 作者姓名： | 林毅利 林志勇 钱浩 LAN Xin-ren |
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| 作者单位： | 华侨大学材料科学与工程学院,福建,泉州,362011 |
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| 基金项目： | 国家自然科学基金，教育部科学技术研究重点项目，福建省自然科学基金 |
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| 摘 要： | 通过阴离子开环聚合法制各纳米二氧化硅／MC尼龙6原位复合材料，采用差示扫描量热法研究MC尼龙6及其原位纳米复合材料非等温结品行为，并利用修正Avrami方程的Jeziomy和Liu的方法进一步处理原位纳米复合材料的非等温结晶动力学，结果表明在纳米二氧化硅／MC尼龙6原位复合材料中，纳米二氧化硅对基体MC尼龙6的结晶有一定的成核作用，并提高了其结品速率。
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| 关 键 词： | 纳米二氧化硅 MC尼龙6 原位复合材料 非等温结晶动力学 |
Non-isothermal crystallization kinetics of Silica /MC nylon6 In Situ Nanocomposites |
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| CAI Li-feng,QIAN Hao,LIN Zhi-yong,LAN Xin-ren.Non-isothermal crystallization kinetics of Silica /MC nylon6 In Situ Nanocomposites[J].Chemical Engineering & Equipment,2009(1):13-17. |
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| Authors: | CAI Li-feng QIAN Hao LIN Zhi-yong LAN Xin-ren |
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| Affiliation: | College of Materials Science and Engineering;Huaqiao University;Quanzhou 362011;China |
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| Abstract: | Silica/MC nylon6 in situ nanocomposites was obtained through anionic ring-opening polymerization. The non-isothermal crystallization of MC nylon6 and its nanocomposites was investigated by means of differential scanning calorimetry(DSC). Results showed that the corresponding crystallization kinetics could be described by the modified Avrami theories(Jeziorny and Liu methods) very well, the introduction of nano silica which acted as nuclei increased the crystallization rates of MC nylon6 matrix. |
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| Keywords: | nano silica MC nylon6 in situ composites non-isothermal crystallization kinetics |
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