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Cs+-Na+离子交换波导的折射率分布分析
引用本文:梁振华,金政武,王恕,蒋幼梅. Cs+-Na+离子交换波导的折射率分布分析[J]. 无机材料学报, 1997, 12(2): 134-142
作者姓名:梁振华  金政武  王恕  蒋幼梅
作者单位:华东理工大学无机材料系!上海,200237,华东理工大学无机材料系!上海,200237,华东理工大学无机材料系!上海,200237,华东理工大学无机材料系!上海,200237
摘    要:用热扩散法和电场辅助扩散法制备了Ca^+-Na^+离子交换玻璃玻导。温度低于玻璃转变温度时,这些波导具有良好的热稳定性。

关 键 词:折射率分析 离子交换 光波导 玻璃 光学玻璃
收稿时间:1996-02-05
修稿时间:1996-04-03

The Refractive Index-Profiles Analysis of Cs+-Na+ Ion Exchange Glass Waveguides
LIANG Zhenhua,JIN Zhengwu,WANG Shu,JIANG Youmei. The Refractive Index-Profiles Analysis of Cs+-Na+ Ion Exchange Glass Waveguides[J]. Journal of Inorganic Materials, 1997, 12(2): 134-142
Authors:LIANG Zhenhua  JIN Zhengwu  WANG Shu  JIANG Youmei
Affiliation:DepartmentofInorganicMatcrials;EastChinaUniversityofScienceandTechnologyShanghai200037China
Abstract:Thc Cs -Na ion exchahgc glass waveguides were made by both thermal diffusion and electrical fieldassista1lt diffusion methods. After the investigation of the temperature depcndence of the waveguides, it wasfound that these waveguides exhibit very high thermal stability below the glass transition temperature. Theion cxchangc mechanism of Cs -Na ion exchange was found to be non-Fick Diffusion. The stress gradientcanscd by the hugc dimension difference for Cs and Na ions, as the electroneutrality field gradientproduced duc to the largc difference in diffusion coefficients between Cs and Na ions predominate thediffusion process in ion exchange. The refractive index prohiles and concentration profiles obtained by SEMand X-ray cnergy dispcrsivc analysis call bc well cxplai11ed by thc proposed ion-exchange mechanism.
Keywords:ion exchange waveguides   Cs~ -Na~ ion exchange   refractive index-profile   ion exchange mechansim  
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