Fabrication of core-shell Fe3O4/polypyrrole and hollow polypyrrole microspheres |
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Authors: | Xiaofeng Lu Hui Mao Wanjin Zhang |
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Affiliation: | Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, People's Republic of China |
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Abstract: | A facile synthesis of highly-regulated core-shell Fe3O4/polypyrrole (PPy) microspheres is achieved using a surfactant directed chemical oxidation polymerization in aqueous solution. The thickness of the PPy layer can be tuned by the quantity of the pyrrole monomer. The formation of core-shell Fe3O4/PPy microspheres lies on the static interactions between the SO3− group in sodium dodecyl sulphate molecules and Fe3O4 microspheres. Other surfactants such as cetyltrimethylammonium bromide and polyoxyethylene (10) isooctylcyclohexyl ether (Triton X-100) directed polymerization cannot produce such highly-regulated core-shell Fe3O4/PPy microspheres. XPS spectra proved the core-shell structure of the composite microspheres. XRD, FTIR, and UV–vis spectra are used to characterize the chemical structure of the composite microspheres. The electrical and magnetic properties are also investigated. Moreover, the obtained core-shell Fe3O4/PPy microspheres can be converted to highly-regulated hollow PPy microspheres by dissolving the Fe3O4 core with acid solution. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers |
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