Gold(I)‐Catalyzed [4+2] Annelation/Nucleophilic Addition Sequence: Stereoselective Synthesis of Functionalized Bicyclo[4.3.0]nonenes |
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| Authors: | Sebastian Bö hringer,Fabien Gagosz |
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| Abstract: | The gold(I)‐catalyzed isomerization of readily available 1,8‐dien‐4‐ynes allows the rapid construction of a variety of synthetically useful bicyclo[4.3.0]nonenes by a stereoselective sequence involving a [4+2] annelation/nucleophilic addition process. |
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| Keywords: | cycloaddition 1,5‐enynes gold homogeneous catalysis polycycles |
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