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Measurement and prediction of the rate of deposition of flocculated asphaltene particles from oil
Authors:M. Jamialahmadi  B. Soltani  H. Müller-Steinhagen  D. Rashtchian
Affiliation:1. University of Petroleum Industry, Ahwaz, Iran;2. Department of Chemical and Petroleum Engineering, Sharif University, Tehran, Iran;3. Institute for Technical Thermodynamics, German Aerospace Centre (DLR), Germany;4. Institute for Thermodynamics and Thermal Engineering, University of Stuttgart, Pfaffenwaldring 6, 70550 Stuttgart, Germany;1. Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte 152, Col. San Bartolo Atepehuacan, Mexico City 07730, Mexico;2. Instituto Politécnico Nacional, CICATA-Legaria, Legaria 694, Col. Irrigación, Mexico City 11500, Mexico;1. Department of Chemical Engineering, Amirkabir University of Technology, Tehran, Iran;2. Department of Chemical Engineering, Islamic Azad University, North Tehran Branch, Tehran, Iran;3. Department of Petroleum Engineering, Amirkabir University of Technology, Tehran, Iran;4. Energy Research Center, Amirkabir University of Technology, Tehran, Iran;5. Institut de Recherche en Génie Chimique et Pétrolier (IRGCP), Paris Cedex, France;6. Thermodynamics Research Unit, School of Engineering, University of KwaZulu-Natal, Howard College Campus, King George V Avenue, Durban 4041, South Africa;7. Département de Génie des Mines, de la Métallurgie et des Matériaux, Faculté des Sciences et de Génie, Université Laval, Québec, (QC) G1V 0A6, Canada;1. Department of Petroleum Engineering, Faculty of Chemical Engineering, Tarbiat Modares University, Tehran, Iran;2. Department of Chemical and Petroleum Engineering, Sharif University of Technology, Tehran, Iran;1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing 102249, China;2. China University of Petroleum-Beijing at Karamay, Karamay 834000, China
Abstract:Asphaltene deposition is one of the unresolved problems in oil industries. Little information is available on the critical question of “how fast” the flocculated asphaltene particles deposit across the production wells from the flowing oil. In this study, the mechanisms of deposition of flocculated asphaltene particles from oil have been studied experimentally and theoretically under forced convective conditions using an accurate thermal approach. The effects of oil velocity, flocculated asphaltene concentration and temperature on the rate of asphaltene deposition are investigated. It is observed that during the first few weeks the deposition mechanism is dominant and the erosion of the deposit is almost negligible. The rate of asphaltene deposition increases with increasing flocculated asphaltene concentration and temperature while it decreases with increasing oil velocity. After clarification of the effects of operating parameters on the deposition process, the results of the experiments are used to develop a mechanistic model for the prediction of the rate of asphaltene deposit formation under forced convective conditions. The predictions of the suggested model for the deposition rate of asphaltene are compared with measured data. Quantitative and qualitative agreement between measured and predicted asphaltene deposition rates is good.
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