Synthesis,characterization of novel silicotungstic acid incorporated SPEEK/PVA-co-ethylene-based composite membranes for fuel cell |
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Authors: | Baskar Ramaganthan P M Sivakumar Sangeetha Dharmalingam |
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Affiliation: | (1) Department of Chemistry, Anna University, Chennai, 600 032, India;(2) Department of Biotechnology, Indian Institute of Technology Madras, Chennai, 600 036, India |
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Abstract: | Sulfonated polyether ether ketone (SPEEK) is prepared by the sulfonation of polyether ether ketone (PEEK). Five of the composite
membranes (PSW1–PSW5) with various percentage compositions of the SPEEK, PVA-co-ethylene, and silicotungstic acid (SWA) were
prepared. The prepared composite membranes were characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray
diffraction (XRD), and thermogravimetric analysis (TGA). Surface morphology of the composite membranes was analyzed using
scanning electron microscopy (SEM). Other evaluations related to conductivities (ion exchange capacity, IEC), proton conductivity),
absorptivity (water and methanol absorption), durability and mechanical properties (tensile strength and percentage elongation)
were also evaluated for the composite membranes. Among the five composite membranes, composite membrane with higher SWA content,
PSW5 (which has 10% SWA) showed more conductivity compared to other membranes. These composites also showed very good conductivities,
mechanical properties, and durabilities. Hence, these composite membranes have the potential to be used in the development
of newer proton exchange membrane fuel cells (PEMFCs). |
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