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Identification of nanominerals and nanoparticles in burning coal waste piles from Portugal
Authors:Joana Ribeiro  Colin R. Ward
Affiliation:
  • a Centro de Geologia, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto, Portugal
  • b Departamento de Geociências, Ambiente e Ordenamento do Território, Faculdade de Ciências, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto, Portugal
  • c School of Biological, Earth and Environmental Sciences, University of New South Wales, Sydney, NSW 2052, Australia
  • d Catarinense Institute of Environmental Research and Human Development, IPADHC, Capivari de Baixo, Santa Catarina, Brazil
  • Abstract:A range of carbon nanoparticles, agglomerates and mineral phases have been identified in burning coal waste pile materials from the Douro Coalfield of Portugal, as a basis for identifying their potential environmental and human health impacts. The fragile nature and fine particle size of these materials required novel characterization methods, including energy-dispersive X-ray spectrometry (EDS), field-emission scanning electron microscope (FE-SEM), and high-resolution transmission electron microscopy (HR-TEM) techniques. The chemical composition and possible correlations with morphology of the nanominerals and associated ultra-fine particles have been evaluated in the context of human health exposure, as well as in relation to management of such components in coal-fire environments.
    Keywords:Douro Coalfield   Coal mining wastes   Trace elements   Combustion   Condensation   Human health
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