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3-甲基-1-苯氧基-9,10-蒽醌及其衍生物的合成和光致变色性
引用本文:胡世荣,刘颖,金正哲.3-甲基-1-苯氧基-9,10-蒽醌及其衍生物的合成和光致变色性[J].延边大学理工学报,2004,30(4):267-269.
作者姓名:胡世荣  刘颖  金正哲
作者单位:[1]漳州师范学院化学系,福建漳州363000 [2]延吉市九中,吉林延吉133000 [3]延边大学理工学院化学系,吉林延吉133002
摘    要:合成了3-甲基-1-苯氧基-9,10-蒽醌、3-甲基-1-对氯苯氧基-9,10-蒽醌、3-甲基-1-对羟基苯氧基-9,10-蒽醌等3种新的光致变色化合物,并通过核磁共振谱、质谱、红外光谱和紫外-可见光谱确定了其结构.通过紫外光谱比较了3种化合物的光致变色性,讨论了苯氧基苯环上被氯和羟基取代时对光致变色性能的影响.

关 键 词:苯氧基蒽醌  苯氧基萘并萘醌  光致变色化合物
文章编号:1004-4353(2004)04-0267-03
修稿时间:2004年9月12日

Synthesis and photochromism of 3-methyl-1-phenoxy-9,10-anthraquinone and its derivation
HU Shi-rong,LIUYing,JIN Zheng-zhe.Synthesis and photochromism of 3-methyl-1-phenoxy-9,10-anthraquinone and its derivation[J].Journal of Yanbian University (Natural Science),2004,30(4):267-269.
Authors:HU Shi-rong  LIUYing  JIN Zheng-zhe
Abstract:In this paper, we reported the synthesis and photochromism of the phenoxyquinones. 3-Methyl-1 phenoxy-9 ,10-anthraqumone, 1-p-chlorophenoxy-3-Methyl-9,10-anthraquinone, 1 -p-hydroxyphenoxy-3-Methyl 9 ,10-anthraqumone have been synthesized. Structures of all above compounds were determined by H-NMR, 13C-NMR, MS, IR, UV-Vis spectroscopy. The photochromism of the phenoxyquinones were determined by UV-Vis spectroscopy. Discusing the relation of the photochromism and Structures.
Keywords:Phenoxyanthraquinones  Phenoxynaphthacenequinones  Photochromic compounds
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