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Influence of residual solvent on physical and chemical properties of amorphous glassy polymer films |
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| Authors: | Julia Kostina Galina Bondarenko Maria Gringolts Alexander Rodionov Olga Rusakova Alexander Alentiev Alexander Yakimanskii Yulia Bogdanova Vladimir Gerasimov |
| Affiliation: | 1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, , Moscow, 119991 Russia;2. Institute of Macromolecular Compounds, Russian Academy of Sciences, , St Petersburg, 199004 Russia;3. Faculty of Chemistry, Moscow State University, , Moscow, 119991 Russia;4. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, , Moscow, 119991 Russia |
| Abstract: | One of the most important areas of current research is the study of the influence of the prehistory of samples of amorphous glassy polymers on their physical and chemical properties. The study of structural changes by high temperature IR spectroscopy compared with of quantum chemical calculations allows for an understanding of the mechanism and nature of such processes. The changes in the structure of the polymer chain depending on the type of solvent used in the formation of the films are demonstrated using the examples of several different classes of polymers. In turn, the impact of such changes in the structure on the physical and chemical properties of the polymer films is demonstrated. © 2013 Society of Chemical Industry |
| Keywords: | non‐covalent interactions residual solvent IR spectroscopy of polymers quantum chemical calculations |