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High Performance Photoswitches Based on Flexible and Amorphous D–A Polymer Nanowires
Authors:Yao Liu  Haifeng Wang  Huanli Dong  Lang Jiang  Wenping Hu  Xiaowei Zhan
Affiliation:1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China;2. Graduate University of Chinese Academy of Sciences, Beijing 100049, PR China
Abstract:A fluorene‐based donor–acceptor conjugated polymer is synthesized and the polymer nanowires are successfully prepared with high quality and large scale using a simple and practical template dipping method. These amorphous polymer nanowires are flexible and show excellent photoconductive properties with reliable reproducibility. The individual nanowire photoswitches exhibit a responsivity as high as 1700 mA W?1 and an on/off ratio as high as 2000 under a light intensity of 5.76 mW cm?2 and a driving voltage of 40 V.
Keywords:conjugated polymers  photoswitches  nanowires  nanodevices
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