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Study on the physical and mechanical properties of electron‐beam‐irradiated Vinyl ester/TiO2 nanocomposites
Authors:Hamzeh Shahrajabian  Seyed Yousef Ahmadi‐Brooghani  Seyed Javad Ahmadi  Mohammad Reza Saeb  Mehdi Moghri
Affiliation:1. Mechanical Engineering Department, Engineering Faculty, Najafabad Branch, Islamic Azad University, Najafabad, Iran;2. Department of Mechanical Engineering, Faculty of Engineering, University of Birjand, Birjand, Iran;3. Nuclear Science and Technology Research Institute, Tehran, Iran;4. Department of Resins and Additives, Institute for Color Science and Technology, Tehran, Iran;5. Polymer Engineering Department, Engineering Faculty, Kashan Branch, Islamic Azad University, Kashan, Iran
Abstract:The effect of electron beam irradiation on the physical and mechanical properties of vinyl ester nanocomposites containing various amounts of TiO2 nanoparticles was investigated. The fracture toughness, surface hardness, and water uptake measurements were carried out to investigate alterations in the physical and mechanical properties owing to electron beam exposure. In this regard, it was attempted to infer the impact of TiO2 nanoparticles on the structural changes varying the irradiation dose. The results were then explained based on crosslinking and chain scission phenomena. Moreover, scanning electron microscopy was used to assess the degree of TiO2 dispersion within the polymer matrix. J. VINYL ADDIT. TECHNOL., 22:110–116, 2016. © 2014 Society of Plastics Engineers
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