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Synthesis and fluorescent properties of europium–polymer complexes containing 1,10-phenanthroline
Authors:Xingyu Liu   Yulin Hu   Baoyan Wang  Zhixing Su  
Affiliation:aInstitute of Polymer and Engineering, College of Chemistry and Chemical Engineering, Lanzhou University, Tianshui South Road 222, Lanzhou 730000, People's Republic of China
Abstract:In this paper, 5-acrylamido-1,10-phenanthroline (AP) was synthesized, then the luminescence material containing Eu–polymer complexes were obtained by two methods. The polymer structure and properties were characterized by FT-IR, UV, fluorescence spectra, DSC, GPC, ICP and XRD. Compared with the two methods the rare earth ions-containing polymers, we obtained copolymer B by the second one that had high and stable fluorescence intensity with the Eu content 0.31%. Comparing the two results via different methods, we have set down the useful basement for the study of the luminescence material containing Eu–polymer complexes.
Keywords:5-Acrylamido-1,10-phenanthroline   Rare earth   Fluorescence   Polymer complex
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