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Effect of Graphene Oxide on Structure and Properties of Impact-Modified Polyamide 6
Authors:Ivan Kelnar  Jaroslav Kratochvíl  Ludmila Kaprálková  Zdeno ?pitálsky  Massimo Uj?i?  Alexander Zhigunov
Affiliation:1. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic;2. Polymer Institute, Slovak Academy of Sciences, Bratislava, Slovakia
Abstract:Modification of polymer blends with nanofillers is an efficient way to improve material parameters. This work deals with application of neat and stearylamine-modified graphene oxide in the polyamide 6/elastomer system using different mixing protocols. Combination of ethene–propene elastomer and graphene oxide leads to a polyamide material with increased strength, stiffness, and toughness. The reason is synergistic effect of the core–shell structure (nanofiller localized at interface) on mechanical properties. The structure-directing effect of graphene oxide is comparable with that of nanoclay. The mechanism of affecting dynamic phase behavior is different as a consequence of graphene oxide nature and interactions with polymer components.
Keywords:Graphene oxide  morphology  polyamide 6  toughness
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