Synthesis and characterization of new pyrochlore solid solution Bi1.5Sb1.5Cu1−xMnxO7

A new pyrochlore solid solution with formula Bi_1.5Sb_1.5Cu_1−xMn_xO₇ has been synthesized using ceramic method at 1000 °C. The cell parameter decreases linearly with increasing manganese concentration. Rietveld refinements for (B_1.5Mn_0.5)(Sb_1.5Mn_0.5)O₇ compound using X-ray powder diffraction data confirmed an overall A₂B₂O₇ cubic pyrochlore structure with a = 10.42749 (4) Å and Fd-3m symmetry. The reliability factors are R_wp = 3.48%; R_p = 2.37%; R_exp = 1.65% and R_Bragg = 1.58%. The magnetic susceptibility measurements achieved between 4 and 300 K indicate a paramagnetic behaviour with an oxidation state “2+” of the manganese ion. The electric resistance measured using complex impedance spectroscopy method put in evidence a decrease of the electric resistance with the temperature, which reached 5 × 10² Ω at 675 K. Dielectric properties depend on the variation of frequency and temperature, results indicate a conductive compound.