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Vertically aligned Fe-doped ZnO nanorod arrays by ultrasonic irradiation and their photoluminescence properties
Authors:Eugene Oh  Kun-Hong Lee  SeGi Yu
Affiliation:a Department of Chemical Engineering, Kyungpook National University, Daegu 702-701, Republic of Korea
b Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-784, Republic of Korea
c Department of Physics, Hankuk University of Foreign Studies, Yongin 449-791, Republic of Korea
Abstract:A facile sonochemical route was demonstrated for the direct fabrication of Fe-doped ZnO nanorod arrays on a Si substrate under ambient conditions. By adding Fe3+ ions in reaction solution, Fe is readily in situ doped into ZnO nanorod arrays via ultrasound irradiation. The morphology and structural characteristic of the Fe-doped ZnO nanorods were investigated using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). And crystal structure was characterized by X-ray diffraction (XRD) spectroscopy. Inductively-coupled plasma atomic emission spectroscopy (ICP-AES) confirmed the Fe-doping of ZnO nanorod arrays with a concentration of 0.9 wt.%. In addition, Fe-doped ZnO nanorod showed the enhancement of photoluminescence (PL) intensity in green-yellow emission.
Keywords:Ultrasound  Zinc oxide  Nanorod  Doping  Photoluminescence
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