Characterization of gas components and deposits in bubbles in silicate glasses prepared with sodium sulphate |
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| Authors: | S. W. Lee K. S. Hong R. A. Condrate Sr R. P. Hapanowicz R. F. Speyer |
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| Affiliation: | (1) University/Industrial Center for Glass Research, New York State College of Ceramics, Alfred University, 14802 Alfred, NY, USA;(2) Present address: Hankuk Glass Research Center, Inchon, South Korea;(3) Present address: Korean Institute of Science and Technology, Seoul, South Korea |
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| Abstract: | The gas contents and surface deposits in bubbles that were formed at various temperatures in sodium calcium silicate glasses using sodium sulphate as a starting material were investigated by means of Raman microprobe and scanning microscopic techniques. Either elemental sulphur or sodium sulphate could be readily detected in the deposits, depending on treatment conditions for the glass. Higher amounts of elemental sulphur were found as deposits on bubble surfaces for glasses prepared using both carbon and sodium sulphate. SO2 or CO2 could be detected as gas components in various bubbles. |
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